Micro‐PIXE determination of Zr in rutile: an application to geothermometry of high‐P rocks from the western Alps (Italy)

AbstractThe Western Alps of Northern Italy mostly consist of lithotectonic units which re‐crystallised and were metamorphosed at high depth in a subduction zone. During their exhumation to shallow crustal levels, however, the high‐pressure (high‐P) mineral assemblages were pervasively re‐equilibrated under low‐pressure (low‐P) conditions, making difficult to estimate the metamorphic thermal peak.Rutile [TiO2] is a typical high‐P mineral, occurring as relict phase in low‐P re‐equilibrated metamorphic rocks. Recent studies suggest that, in thermodynamic systems buffered by the occurrence of quartz and zircon in the rock, Zr content in rutile is a temperature–dependent function that can be modelled quantitatively.An application of rutile Zr‐geothermometer to continental and oceanic rocks of the Western Alps, pervasively re‐equilibrated under low‐P conditions, is presented.The selected rutile crystals were analysed by PIXE using a microbeam set‐up at the LABEC laboratory of INFN in Florence. The PIXE spectra and maps were processed by Geopixe software package. Micro‐PIXE analyses allowed determining the concentration and the distribution of Zr.Results obtained by applying the rutile Zr‐geothermometer gave a more precise indication about the temperatures of the metamorphic conditions suffered by Alpine metamorphic rocks with respect to phase relations and conventional geothermometry, showing that determination of Zr concentration by micro‐PIXE technique is a useful tool to reconstruct metamorphic events.The continental units, outcropping in separate zones of Western Alps, show two slightly different thermal peaks (Tmean = 530 ± 10 °C and Tmean = 555 ± 10 °C) for the same metamorphic event. The oceanic units provide Tmean estimates of 575 ± 10 °C slightly higher than the continental units. Copyright © 2008 John Wiley & Sons, Ltd

Syn-exhumation coupling of oceanic and continental units along the western edge of the alpine corsica: A review

The Alpine Corsica represents a segment of the Alpine collisional belt. In its western edge, it is characterized by the close association of continental units deformed under high-pressure metamorphic conditions (Lower Units) and oceanic units showing a metamorphism ranging from high-pressure (Schistes Lus-trés Complex) to very low-grade conditions (Upper Units). This paper provides a complete review of the relationships between the continental and oceanic units in selected five areas where the stratigraphic features, deformation history, metamorphic P-T path and tectonic setting are available for each unit. The collected data indicate that the oceanic units occur not only at the top of the continental ones, as generally proposed in the literature, but also intercalated within them. Such relationships were achieved at shallow structural level during the late stage of exhumation, when the continental units were tectonically coupled with the oceanic units which were dragged as slices from the orogenic wedge. The coupling probably occurred immediately before the transition from syn-to post-orogenic geodynamic regime that affected the whole Alpine-Apennine collisional system in the early Oligocene. After the coupling, the stack of oceanic and continental units experienced a further exhumation-related deformation before their final exposure at the surface

Structure, tectonics and metamorphic development of the Sancti Spiritus Dome (eastern Escambray massif, Central Cuba)

The Sancti Spiritus Dome of the eastern Escambray (Cuba) represents a metamorphic fold and thrust structure which was part of the Cretaceous subduction-accretion complex of the Greater Antillean Arc. On the basis of structural data and pressure-temperature-time evolution the metamorphic complex can be subdivided into four units interpretable as nappes: a high-grade greenschist-facies unit (Pitajones unit), a high-pressure tectonic mélange (Gavilanes unit), high-pressure amphibolites (Yayabo unit) and - tectonically overlying - low-pressure metagabbros of the Greater Antillean Arc (Mabujina unit). The oldest rock fabrics are preserved in eclogite- and blueschist-facies rocks of the Gavilanes unit, indicating arc-parallel extension. Maximum metamorphic conditions are recorded in eclogites (16-20 kbar, 580-630 °C) and garnet-mica schists (16-23 kbar, 530-610 °C) of the Gavilanes unit. Field observations and fabric studies show that greenschist-facies dynamic indicators are dominated by top-to-NE tectonic transport in the lowermost nappes. The greenschist-facies shear zone between the Yayabo unit and the Mabujina unit is viewed as the main detachment zone between the subduction complex and the overlying arc complex. Active subduction ceased at about 70 Ma, followed by rapid uplift, exhumation and thrusting to the north

The pioneer work of Bernard Kübler and Martin Frey in very low-grade metamorphic terranes: paleo-geothermal potential of variation in Kübler-Index/organic matter reflectance correlations. A review

Low-temperature metamorphic petrology occupies the P-T field between sedimentary and metamorphic petrology. Two important pillars of low-temperature metamorphism are coal petrology and clay mineralogy. When low temperature petrology was established bridging a hiatus between the two classical geological disciplines of sedimentary geology and metamorphic petrology, geologists faced a need for the usage of different terminology tenets. Martin Frey and Bernard Kübler were two pioneers in low-grade metamorphic petrology. They focused their research on clarifying the relationships of clay mineralogy and organic petrology to metamorphic pressure (P) and temperature (T) conditions. The ultimate aim of M. Frey and B. Kübler was to establish a correlation between clay indices and organic parameters for different geodynamic setting and therefore for various pressure-temperature (P-T) conditions occurring in low grade metamorphic terranes. For this purpose, a special attention was addressed to the correlation between the Kübler-Index (KI) and vitrinite reflectance (VR). All these efforts are dedicated to estimate the P-T conditions and thus to gain insight into the geodynamic evolution of low-grade metamorphic terranes. B. Kübler and M. Frey honored here concentrated their studies to the Helvetic Central Alps area. The very low-grade Helvetic domain is therefore of basic interest of this paper. Ensuing the extensive compilation of data from the Helvetic domain, a reinterpretation of Kübler and Frey's research is presented in the light of last decade's scientific progress. A comprehensive dataset available enables to discriminate many factors influencing the Kübler-Index and organic-matter reflectance alongside to time, temperature and pressure. The correlation is restricted to the KI and organic matter reflectance (mostly VR) because most of the studies used both methods. Organic matter reflectance (OMR) includes data from vitrinite reflectance and bituminite reflectance measurements. Geodynamics has important control on the KI/VR (OMR) correlation. Tectonic units having a similar geodynamic evolution are featured by the comparable KI/OMR trends, related to the particular paleo-geothermal conditions. Obviously the KI/OMR correlations provide a mean to characterise geothermal gradients and metamorphic very-low-grade pressure-temperature conditions. In terranes where high deformations rates are reported, exceeding the high anchizone conditions, strain promotes the kinetic effects of temperature and pressure on the KI versus OMR rati

Integration of natural data within a numerical model of ablative subduction: A possible interpretation for the Alpine dynamics of the Austroalpine crust

A numerical modelling approach is used to validate the physical and ge- ological reliability of the ablative subduction mechanism during Alpine con- vergence in order to interpret the tectonic and metamorphic evolution of an inner portion of the Alpine belt: the Austroalpine Domain. The model pre- dictions and the natural data for the Austroalpine of the Western Alps agree very well in terms of P-T peak conditions, relative chronology of peak and exhumation events, P-T-t paths, thermal gradients and the tectonic evolu- tion of the continental rocks. These findings suggest that a pre-collisional evolution of this domain, with the burial of the continental rocks (induced by ablative subduction of the overriding Adria plate) and their exhumation (driven by an upwelling flow generated in a hydrated mantle wedge) could be a valid mechanism that reproduces the actual tectono-metamorphic config- uration of this part of the Alps. There is less agreement between the model predictions and the natural data for the Austroalpine of the Central-Eastern Alps. Based on the natural data available in the literature, a critical discus- sion of the other proposed mechanisms is presented, and additional geological factors that should be considered within the numerical model are suggested to improve the fitting to the numerical results; these factors include varia- tions in the continental and/or oceanic thickness, variation of the subduction rate and/or slab dip, the initial thermal state of the passive margin, the oc- currence of continental collision and an oblique convergence.Comment: 11 Figures and 3 Tabe

Late Cenozoic metamorphic evolution and exhumation of Taiwan

The Taiwan mountain belt is composed of a Cenozoic slate belt (Hsuehshan Range units, HR, and Backbone Slates, BS) and of accreted polymetamorphic basement rocks (Tananao Complex, TC). Ongoing crustal shortening has resulted from the collision between the Chinese continental margin and the Luzon volcanic arc, which initiated ~6.5 Ma ago. The grade and age of metamorphism and exhumation are a key record of the development of the orogenic wedge. Because the Taiwan mountain belt is mostly composed by accreted sediments lacking metamorphic index minerals, quantitative constraints on metamorphism are sparse. By contrast, these rocks are rich in carbonaceaous material (CM) and are therefore particularly appropriate for RSCM (Raman Spectroscopy of CM) thermometry. We apply this technique in addition to (U-Th)/He thermochronology on detrital zircons to assess peak metamorphic temperatures (T) and the late exhumational history respectively, along different transects in central and southern Taiwan. In the case of the HR units, we find evidence for high metamorphic T of at least 340°–350°C and locally up to 475°C, and for relative rapid exhumation with zircon (U-Th)/He ages in the range of 1.5–2 Ma. Farther east, the BS were only slightly metamorphosed (T < 330 °C), and zircons are not reset for (U-Th)/He. From the eastern BS to the inner TC schists, T gradually increases from ~350°C up to ~500°C following an inverted metamorphic gradient. Available geochronological constraints and the continuous thermal gradient from the BS to the basement rocks of the TC suggest that the high RSCM T of the TC were most probably acquired during the last orogeny, and were not inherited from a previous thermal event. Zircons yield (U-Th)/He ages of ~0.5–1.2 Ma. Peak metamorphic T and the timing of exhumation do not show along-strike variations over the TC in the studied area. In contrast, exhumation is laterally diachronous and decreases southward in the case of the HR units. In particular, our data imply that the HR units have been exhumed by a minimum of 15 km over the last few Ma. In the case of the BS, they show far less cumulated exhumation and much slower cooling rates. We propose that most of the deformation and exhumation of the Taiwan mountain belt is sustained through two underplating windows located beneath the Hsuehshan Range and the TC. Our data show significant departures from the predictions of the prevailing model in Taiwan, which assumes a homogeneous critical wedge with dominant frontal accretion. Our study sheds new light on how the mountain belt has grown as a possible result of underplating mostly

Post-orogenic extension and metamorphic core complexes in a heterogeneous crust: the role of crustal layering inherited from collision. Application to the Cyclades (Aegean domain)

International audienceThe development of metamorphic core complexes (MCC) corresponds to a mode of lithospheric continental stretching that follows collision. In most of the models that explain the formation of the MCC, high thermal gradients are necessary to weaken the lower crust and to induce its ascent. Such models fail to explain the exhumation of high pressure-low temperature metamorphic rocks in metamorphic core complex structures as observed in the Cycladic Blueschists in the Aegean domain. Besides, account for the lithological crustal stratification induced from collision has never been tested. In this paper, we use fully coupled thermomechanical modelling to investigate the impact of structural heritage and initial thermal gradient on the behaviour of the post-orogenic continental lithosphere. The models are designed and validated by petrological, structural and time data from the Cyclades. As a result, high thermal gradients (Moho temperature higher than 800°C) are neither necessary nor always sufficient to induce the development of a metamorphic core complex. At the contrary, the rheological layering of the crust inherited from collision is a first-order parameter controlling the development of extensional structures in post-orogenic settings. 'Cold' MCC can develop if the crust is made of a strong nappe thrust on top of weaker metamorphic cover and basement units, as observed in the Cyclades

The Mesozoic along-strike tectono-metamorphic segmentation of Longmen Shan (eastern Tibetan plateau)

The Longmen Shan belt (eastern border of the Tibetan plateau) constitutes a tectonically active region as demonstrated by the occurrence of the unexpected 2008 Mw 7.9 Wenchuan and 2013 Mw 6.6 Lushan earthquakes in the central and southern parts of the belt respectively. These events revealed the necessity of a better understanding of the long‐term geological evolution of the belt and its effect on the present dynamics and crustal structure. New structural and thermobarometric data offer a comprehensive dataset of the paleo‐temperatures across the belt and P‐T estimates for low‐grade metamorphic domains. In the central Longmen Shan, two metamorphic jumps of 150‐200°C, 5‐6 kbar and ~50 °C, 3‐5 kbar acquired during the Early Mesozoic are observed across the Wenchuan and Beichuan faults respectively, attesting to their thrusting movement and unrevealing a major decollement between the allochtonous Songpan‐Garze metasedimentary cover (at T > 500°C) and the autochtonous units and the basement (T < 400°C). In the southern Longmen Shan, the only greenschist‐facies metamorphism is observed both in the basement (360 ± 30°C, 6 ± 2 kbar) and in the metasedimentary cover (350 ± 30°C, 3 ± 1 kbar). Peak conditions were reached at c. 80‐60 Ma in the basement and c. 55‐33 Ma in the cover, c. 50 Ma after the greenschist‐facies metamorphic overprint observed in the central Longmen Shan (c. 150‐120 Ma). This along‐strike metamorphic segmentation coincides well with the present fault segmentation and reveals that the central and southern Longmen Shan experienced different tectono‐metamorphic histories since the Mesozoic

Mountain building in Taiwan: A thermokinematic model

The Taiwan mountain belt is classically viewed as a case example of a critical wedge growing essentially by frontal accretion and therefore submitted to distributed shortening. However, a number of observations call for a significant contribution of underplating to the growth of the orogenic wedge. We propose here a new thermokinematic model of the Taiwan mountain belt reconciling existing kinematic, thermometric and thermochronological constraints. In this model, shortening across the orogen is absorbed by slip on the most frontal faults of the foothills. Crustal thickening and exhumation are sustained by underplating beneath the easternmost portion of the wedge (Tananao Complex, TC), where the uplift rate is estimated to ~6.3 mm a^(−1), and beneath the westernmost internal region of the orogen (Hsueshan Range units, HR), where the uplift rate is estimated to ~4.2 mm a^(−1). Our model suggests that the TC units experienced a synchronous evolution along strike despite the southward propagation of the collision. It also indicates that they have reached a steady state in terms of cooling ages but not in terms of peak metamorphic temperatures. Exhumation of the HR units increases northward but has not yet reached an exhumational steady state. Presently, frontal accretion accounts for less than ~10% of the incoming flux of material into the orogen, although there is indication that it was contributing substantially more (~80%) before 4 Ma. The incoming flux of material accreted beneath the TC significantly increased 1.5 Ma ago. Our results also suggest that the flux of material accreted to the orogen corresponds to the top ~7 km of the upper crust of the underthrust Chinese margin. This indicates that a significant amount (~76%) of the underthrust material has been subducted into the mantle, probably because of the increase in density associated with metamorphism. We also show that the density distribution resulting from metamorphism within the orogenic wedge explains well the topography and the gravity field. By combining available geological data on the thermal and kinematic evolution of the wedge, our study sheds new light onto mountain building processes in Taiwan and allows for reappraising the initial structural architecture of the passive margin

Post-depositional tectonic modifications of VMS deposits in Iberia and its economic significance

The original stratigraphic relationships and structure of VMS deposits are commonly obscured by deformation. This can also affect their economic significance, as shown by several Iberian Pyrite Belt (IPB, SW Iberia) examples. The contrasting rheologic properties of the different lithologies present in an orebody (massive sulphide, feeder stockwork, alteration envelope, volcanic and sedimentary rocks) playa major role in determining its overall behaviour. Variscan thin-skinned tectonics led to stacking of the massive pyrite and stockwork bodies in duplex structures, resulting in local thickening and increased tonnage of minable mineralization. Furthermore, differential mechanical behaviour of the different sulphide minerals localised the detachments along relatively ductile sulphide-rich bands. The result was a geochemical and mineralogical reorganisation of most deposits, which now consist of barren, massive pyrite horses, bounded by base metal-rich ductile shear zones. Metal redistribution was enhanced by mobilisation of the base metal sulphides from the initially impoverished massive pyrite, through pressuresolution processes, to tensional fissures within the already ductile shear zones. In NW Iberia, VMS deposits were also strongly overprinted by the Variscan deformation during emplacement of the Cabo Ortegal and Órdenes allochthonous nappe complexes, but no stacking of the orebodies was produced. Original contacts were transposed, and the orebodies, their feeder zones and the country rock acquired pronounced laminar geometry. In lower-grade rocks (greenschist facies, Cabo Ortegal Complex), solution transfer mechanisms are common in pyrite, which remains in the brittle domain, while chalcopyrite shows ductile behaviour. In higher-grade rocks (amphibolite facies, Órdenes Complex), metamorphic recrystallisation overprints earlier deformation textures. The contrasting behaviour of the IPB and NW Iberian deposits is explained by key factors that affect their final geometry, composition and economics, such as pre-deformation structure, size and mineralogical composition of the orebody and associated lithologies, temperature, crustal level, deviatoric stress and availability of a fluid phase during deformation and the style and rate of deformation